What makes micas
so important to command such a unique position ? Because it had been gifted
with exceptional values. It possesses some of the most outstanding combination
of chemical, physical, electrical, thermal and mechanical properties which
are not found in any other product.
Processing
The ordinary
mica crystals as they come out of a mine is in form of rough books or lumps
of irregular shape, size and thickness, associated with impurities and
structural imperfections. They have to undergo a long operation of cutting,
sorting and processing from crude to commercial quality. The waste resulting
from the production of crude to commercially useful sheet mica forms about
90 per cent Some times even the total output of mica from a mine is sold
as scrap mica and it can be used as Mica Scrap or can be used for Grinding
Mica Powder.
No machine has
yet been designed to process mica mechanically. The processing technique,
therefore, involves only a pair of hands, eyes and a simple knife. The
operations performed consists of cobbing or cleaning the crude crystals
as extracted from the mine with its associated impurities; rifting or splitting
the cobbed mica into usable sheets by sickle and then by sharp knife removing
major flaws and structural imperfections, such as cracks, holes, reeves,
crossgrains and other physical defects to obtain the maximum usable area
with minimum wastage. The trimming of mica is a skilled hand-operation
in which cracks and imperfections are removed at the edges of the sheets
using a knife while saving the best area of usable sheet. The knife-dressed
sheet mica of irregular polygonal shapes is finally graded into different
standard sizes and commercial qualities before they are offered for marketing.
Classification
For commercial
and industrial purpose natural mica are mainly divided into three catagories,viz
:
1. Processed Mica 2. Fabricated Mica 3. Manufactured Mica.
Processed Mica is fundamentally a natural sheet mica of an irregular size and polygonal shapes that is relatively flat and free from physical defects and structural imperfections having a minimum usable area of 4.8 sq. cm. (0.75 sq. inch), suitable to be cut, punched or stamped into specific size and shape chiefly for use by the electronic and electrical industries.
Fabricated Mica is basically a natural sheet mica cut, stamped or punched to specified size, shape and thickness for industrial and uses, such as; discs, washers, cut-films or sheets, joints, backing plates, plates, spacers, mica formers for irons, toasters, rice-cookers, etc.
Manufactured
Mica means mica-based products manufactured from natural mica, such
as, micanite or built-up mica, mica paper, mica heating elements, mica
capacitors, mica flakes and powder, mica bricks, etc.
Quality grading
of mica
The quality classification
of mica, is based visual tests, depends on individual opinion. Also products
of different mines vary in physical characteristics to such an extent that
the development of a single standard with reasonable
limits of tolerance becomes an acutely dificult task. Added to these difficulties
are the facts that quality clasification has to be carried out by a large
number of individual workers, and that it is highly influenced by such
circumstantial factors as lighting conditions, mood of the inspector, etc.
Under these circumstances any standard for quality classification of mica,
such as the one described in this standard can give at
best an approximate idea of a particular quality and its relative position
with respect to other qualities. As such,
the quality of mica depends upon the and the seller who have to work out
a basis on mutual understanding
and peculier requirements of the industrial applications. The application
of common sense to the task of procurement is therefore always helpful
especially so in the matter of choosing a right supplier as only an experienced
supplier knowing the individual buyer’s specific requirements, is able
to deliver to the near correct material. In fact, it is an expert’s job
to process and assort mica to suit to individual buyers requirements and
maintain uniform and satisfactory supplies on a regular basis.
Technical
data of mica
Physically
Mica is transparent, optically flat, easily splittable into thin films
along its cleavage, colourless in thin sheets, resillient and incompressible.
Chemically
Mica is a complex hydrous silicate of aluminium containing potassium, magnesium,
iron, sodium fluorine and/or lithium and also traces of several other elements,
It is stable and completely inert to the action of water, acids (except
hydro-fluoric and concentrated sulphuric), alkalies, conventional solvents,
oils and is virtually unaffected by atmospheric action.
Electrically
Mica has the unique combination of great dielectric strength, uniform dielectric
constant and capacitance stability, low power loss (high Q factor), high
electrical resistivity and low temperature co-efficient and capacitance.
It is noted for its resistance to arc and corona discharge with no permanent
injury, and has little or no effect when exposed to electronic radiation
dosages upto 1018 nvt. Thus maintaining its a-c dielectronic
material when exposed to the oxidising action of electrical discharges
either on the surface or within internal gas spaces in built-up mica insulation.
Thermally
Mica is fireproof, infusable, incombustible and non-flammable and can resist
temperatures of 600° C to 900° C (1112° F to 1652° F) depending
on the type of mica. It has low heat conductivity, excellent thermal stability
and may be exposed to high temperatures without noticeable effect.
Mechanically
Mica is relatibility soft and can be hand-cut, machined or die-punched.
It is flexible, elastic and tough, having high tensile strength. It can
withstand great mechanical pressure perpendicular to plane but the lamination
have weak cleavage and can be easily split into very thin leaves.
| Characteristic | Source | MUSCOVITE | PHILOGOPITE |
| Colour - Ruby, Green, White Amber, Yellow, Silver | |||
| Density
gm/cm³
ib/in³ |
1
1 |
2.6-3.2
0.095-0.116 |
2.6-3.2
0.095-0.116 |
| Specific Heat | 1 | 0.21 | 0.21 |
| Hardness
Moh scale
Shore test |
1
1 |
2.8-3.2
80-105 |
2.5-3.0
70.100 |
| Optic Axial Angle | 1 | 55-75 | 5-25 |
| Tensile
strength
kgf/cm²
ibf/in² |
2
2 |
about
1750
about 25000 |
about
1000
about 15000 |
| Shear
Strength
kgf/cm²
ibf/in² |
2
2 |
2200-2700
31000-38000 |
1000-1300
14000-19000 |
| Compression
Strength kgf/cm²
ibf/in² |
3
3 |
1900-2850
27000-32000 |
---
--- |
| Modulus
od Elasticity kgf/cm² x10-³
ibf/in² x10-6 |
2
2 |
1400-2100
20-30 |
1400-2100
20-30 |
| Coefficient of expansion per C Perpendicular to cleavage plane | 4 | 9x10-6 -36x10-6 | 30x10-6 -60x10-6 |
| Calcining
Temperature C
F |
3
3 |
700-800
1290-1470 |
900-1000
1650-1830 |
| Maximum
Operating Temperature C
F |
3
3 |
500-600
930-1110 |
800-900
1470-1650 |
| Thermal
Conductivity Perpendicular to cleavage planes
Gm.cal/sec/cm² /C/cm BTU/hr/ft² /° F/ft |
1
1 |
about
0.0013
about 0.31 |
about
0.001
about 0.24 |
| Parallel
to cleavage planes
Gm.cal/sec/cm² /° C/cm BTU/hr/ft² /° F/ft |
5
5 |
---
--- |
about
0.012
about 3.0 |
| Water of Constitution % | 1 | 4.5 | 3.0 |
| Moisture Absorption | 3 | very low | very low |
| Apparent
Electric Strength 0.001" to kv/mm
0.003" thick Volts per 0.001" R.M.S. at 15C (60 F) 0.01" to kv/mm 0.05" thick Volts per 0.001" |
1
1 1 1 |
120-200
3000-5000 40-80 1000-2000 |
---
--- 30-60 750-1500 |
| Permittivity (a 15 C (60° F) | 3 | 6-7 | 5-6 |
| Power Factor (loss Tangent) 15 C (60° F) | 3 | 0.0001-0.0004 | 0.001-0.005 |
| Volume Resistivity 25 C (77 ° F) Ohm cm | 1.3 | 4x1013 -2x1017 | 1x1012 -1x1014 |
| Acid Reaction | 1 | Affected
by
Hydrofluoric Acid |
Affected
by
Sulphuric Acid |
| Source 1 . | "Mica
& Micanite. A Critical Resume of Available Information". E.R.A. Report
D/T 18 1934, by D.V. Onslow. |
| Source 2 | "Report on the Mechanical Properties of Mica" ERA Report D/T 13 1924. |
| Source 3 |
"Insulating
Materials for Design and Engineering Practice" by F.M. Clark Joihn Wlley
& Sons Inc. New York, 1962. |
| Source 4 | "Some
Physical Properties of Mica", Journal of National Bureau of Standards.Volume
35,
October 1945, p.309,by P Hidnert and G. Dickson. |
| Source 5 | "Thermal
Conduction in Mica along the planes of Cleavage". by H.J. Goldmid and
A . E . Bowley. Letter in Nature, Vol. 187, 3rd September 1960, p 864. |
Uses and applications
of natural sheet mica based on dielectric, optical, mechanical, electrical
and thermal properties or their combination :
| Commercial Quality | Applications |
| V-1
Ruby Clear
V-2 Ruby Clear & S.S. V-3 Ruby Fair Stained V-4 Ruby Good Stained V-5 Ruby Stained "A" V-6 Ruby AQ V-14 Green / Brown V-14 1st Quality |
Uses
Based on dielectric properties :
High precision electronic capacitors (fixed & trimmer) for transmission of radio waves e.g. for Radio, and Guided Missiles, etc. Microwave transmission attenuators. Microwave tube Windows. Windows for geiger counter tube for measuring soft radiations detecting radio activity. X-ray apparatus and similar devices requiring protection from heat. Space Rockets. Telestar transmission Jet engine ignition systems Target and mosaic micas used in telecasting industry in image orthocones and computer matrix. Radiation insulation. Uses based
on optical properties :
Uses based
on Mechanical properties :
|
| V-5
Ruby Stained "A"
V-7 Ruby Stained "B" V-8 Ruby BQ V-9 Ruby Heavy Stained V-15 Green / Brown V-15 2nd Quality V-16 Green / Brown V-16 Std. Or BQ |
Uses
based on Electrical Properties :
Bridges and supports for radio, television and electronic Tubes, television cathod ray tubes, hearing aid tubes,audion tubes, acron tubes, miniature tubes, incandescent lamps, etc. Low precision and receiver condencers. Backing plates for capacitors. Interlayer insulation in high temperature air-cooled transformer coils. Supports for heating filaments of high power electric lamps. Insulation for Magnetos in ignition systems of internal combustion engines of submarines, aeroplanes, automobiles, trucks, military tanks, etc. Wrappers, shields and washers for spark plugs. Transistor Mounting Washers. Strainer Cores & Skin Gates for sand castings. Punched mica parts for Computers, Televisions, Radios, Car-ignitions and other semi-conductors and electronic components. Uses based
on optical-cum-mechanical properties :
|
| V-9
Ruby Heavy Stained
V-10 Ruby Densely Stained V-11 Black Dotted V-12 Black Spotted V-13 Black/Red Stained |
Uses
based on the thermal properties :
Various domestic electric heating applicances requiring non-inflammability and dielectric resistivity,viz. Cooking ranges, electric flat-irons, toasters, coffee perculators, kettles, ovens, rectifiers, soldering, irons, griddles, water heaters, radiaters, boilers, hair dryers, lead melting vats,glue pots, and host of other household appliances. Commutator segment insulation and armature insulation in motors and generators that are fully enclosed to exclude dust and moisture and those that are to be used in a very hot climate at high operating temperature. Solenoid insulation in electric motors and generators. Insulating washers, discs and terminal plates for dynamos, commutators, transformers, electric motors, generators, lightning arresters, fuse boxes, induction coils, grid rheostats and numerous other electrical devices. |